This seems like a great list and didn’t want to lose track of it, so thought I would post it here.
Top 10 things to deepen your already existing knowledge on Windows Azure:
1. Windows Azure Training Kit: A comprehensive set of resources covering PaaS and IaaS workloads, including presentations, hands-on-labs, demos, and scripts so that you and your team may learn and re-deliver information to your customers about Windows Azure.
2. Windows Azure Track: A comprehensive set of online trainings broken down by role (sales, pre-sales, architect, developer)
3. Moving Applications to the Cloud: Provides an introduction to Windows Azure and discusses the cost model and application life cycle management for cloud-based applications, and describes how to migrate an existing ASP.NET application to the cloud.
4. Developing Applications for the Cloud: Discusses the design considerations and implementation details of applications that are designed from the beginning to run in the cloud.
5. Building Hybrid Applications on Windows Azure: Covers many topics related to architecting applications which rely on cloud AND on-premise technology (for example, an application that contains some components or features that cannot be located in the cloud, such as third-party services or sensitive data that must be maintained onsite under specialist control).
6. Building Elastic and Resilient Cloud Applications: Self-explanatory description.
7. A Guide to Claims-Based Identity and Access Control: Self-explanatory description.
8. Cloud Ninja: A comprehensive code sample on codeplex developed to demonstrate the design and implementation of key features in Windows Azure with emphasis on metering and automated scaling.
9. Fabrikam Shipping: Provides an in depth coverage of Identity Federation for multi-tenant applications. This is recommended to be reviewed in addition to Cloud Ninja.
10. Windows Azure Forums: An online community of very responsive Azure users who help each other out with common questions, code samples, and other general technical support.